Conventional hydrofunctionalization of α-olefins with mineral acids proceeds with Markovnikov selectivity to afford branched isomers. The direct formation of linear constitutional isomers is ...
In our design, homolytic cleavage of the preassociated Cl–Fe bond of the higher-valent iron species produces chlorine radical I and lower-valent iron species via an LMCT process. The reactive chlorine ...
(Phys.org)—A team of researchers at the California Institute of Technology has used a modified enzyme to provide better anti-Markovnikov selectivity in alkene oxidations. In their paper published in ...
Oxidizing the end carbon atom of a terminal alkene to form an aldehyde, a process called anti-Markovnikov alkene oxidation, is difficult because the reaction is energetically unfavorable. The ...
The selective conversion of alkenes into alcohols is a cornerstone of modern chemical synthesis, underpinning the production of pharmaceuticals, functional materials, and fine chemicals. However, ...
Liang Deng's group at the Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, recently discovered that a dinuclear cobalt carbonyl complex [(Xantphos)Co 2 (CO) 6] coordinated by the ...
Chemists have been trying for some time to find a practical synthetic method that the chemical industry could use to add terminal functional groups such as alcohols, ethers, and amines to olefins.
The selective conversion of alkenes into alcohols is a cornerstone of modern chemical synthesis, underpinning the production of pharmaceuticals, functional materials, and fine chemicals. However, ...
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